Sam Raimi Director Tobey Maguire Peter Parker , Spider-Man Actor Kirsten Dunst Mary Jane Watson Actor James Franco Harry Osborn Actor Alfred Molina Dr Otto Octavius , Doc Ock Actor Rosemary Harris May Parker Actor Donna Murphy Rosie Octavius Actor J.K. Simmons J Jonah Jameson Actor Laura Ziskin Producer Avi Arad Producer Alfred Gough Writer Miles Millar Writer Michael Chabon Writer Alvin Sargent Screenwriter Joseph M. Caracciolo Executive Producer Kevin Feige Executive Producer Stan Lee Executive Producer Bill Pope Cinematographer Bob Murawski Film Editing Danny Elfman Original Music Neil Spisak Production Design Steve Saklad Art Director Thomas Valentine Art Director Jay Hart Set Decoration James Acheson Costume Design Gary Jones Costume Design Dianne Crittenden Casting