Aimee Carrero Princess Elena Voice Jenna Ortega Princess Isabel Voice Chris Parnell Jaquins Migs Voice Yvette Nicole Brown Luna Voice Carlos Alazraqui Skylar Voice Emiliano Díez Francisco Voice Julia Vera Luisa Voice Christian Lanz Chanecellor Esteban Voice Jillian Rose Reed Naomi Voice Joseph Haro Mateo Voice Jorge Diaz Gabe Voice Keith Ferguson Zuzo Voice Joseph A. Nunez Armando Voice Sofia Carson Maliga Guest Voice Rachel Brosnahan Princess Chloe Guest Voice Jamie-Lynn Sigler Princess Rebeca Guest Voice Chrissie Fit Princess Valentina Guest Voice Craig Gerber Executive Producer