Aimee Carrero Princess Elena Voice Jenna Ortega Princess Isabel Voice Chris Parnell Jaquins Migs Voice Yvette Nicole Brown Luna Voice Carlos Alazraqui Skylar Voice Emiliano Díez Francisco Voice Julia Vera Luisa Voice Christian Lanz Chanecellor Esteban Voice Jillian Rose Reed Naomi Voice Joseph Haro Mateo Voice Jorge Diaz Gabe Voice Keith Ferguson Zuzo Voice Joseph A. Nunez Armando Voice Gina Rodriguez Princess Marisa Guest Voice Edward James Olmos King Pescoro Guest Voice Rita Moreno Queen Camila Guest Voice Prince Royce Prince Marzel Guest Voice Rosario Dawson Daria Guest Voice Steve Buscemi Saloso Guest Voice Ralph Garman Torpe Guest Voice Craig Gerber Executive Producer