Finn Atkins Charlotte Brontë Actor Chloe Pirrie Emily Brontë Actor Charlie Murphy Anne Brontë Actor Jonathan Pryce Patrick Brontë Actor Adam Nagaitis Branwell Brontë Actor James Norton Duke of Wellington Actor Matt Adams Captain Parry, Jack Sharp Actor Kris Mochrie Captain Ross Actor Jonathon Carley Napoleon Bonaparte Actor June Watson Tabby Aykroyd Actor Mark Frost John Brown Actor Sally Wainwright Director, Writer, Executive Producer Matthew Read Executive Producer Faith Penhale Executive Producer Rebecca Eaton Executive Producer