Aimee Carrero Princess Elena Voice Jenna Ortega Princess Isabel Voice Chris Parnell Jaquins Migs Voice Yvette Nicole Brown Luna Voice Carlos Alazraqui Skylar Voice Emiliano Díez Francisco Voice Julia Vera Luisa Voice Christian Lanz Chanecellor Esteban Voice Jillian Rose Reed Naomi Voice Joseph Haro Mateo Voice Jorge Diaz Gabe Voice Keith Ferguson Zuzo Voice Joseph A. Nunez Armando Voice Mario López Cruz Guest Voice Diane Guerrero Vestia Guest Voice Jane Fonda Shuriki Guest Voice Héctor Elizondo Fiero Guest Voice Lou Diamond Phillips Victor Guest Voice Rosie Perez Dulce Guest Voice Cheech Marin Quitz Moz Guest Voice Craig Gerber Executive Producer